Whiteboard Chemistry with Joe White

AQA A-Level
Chemistry.

Written by an A Level examiner

Comprehensive revision notes for AQA AS and A-Level Chemistry (7404/7405), organised by Physical, Inorganic and Organic chemistry, with all 12 required practicals collated on one page.

AQA 7404/7405
A2 Examined at full A-Level only (typically Year 13) — everything else is AS & A-Level (Year 12)

Physical chemistry

Sections 3.1.1–3.1.12. Each card shows its A-Level paper; Paper 3 can examine any content. Equilibrium constant Kp (3.1.10) is covered on the equilibria page.

3.1.1 · Paper 1

Atomic Structure

Fundamental particles, mass number and isotopes, time-of-flight mass spectrometry, electron configuration and ionisation energies.

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3.1.2 · Papers 1 & 2

Amount of Substance

The mole and the Avogadro constant, the ideal gas equation, empirical and molecular formulae, balanced equations, titrations, yields and atom economy.

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3.1.3 · Papers 1 & 2

Bonding

Ionic, covalent, dative and metallic bonding; shapes of molecules and ions; electronegativity, polarity and intermolecular forces.

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3.1.4 · Papers 1 & 2

Energetics

Enthalpy change, calorimetry, Hess’s law and bond enthalpies.

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3.1.5 · Paper 2

Kinetics

Collision theory, the Maxwell–Boltzmann distribution, and the effects of temperature, concentration and catalysts on reaction rate.

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3.1.6 + 3.1.10 · Papers 1 & 2

Chemical Equilibria, Kc and Kp

Dynamic equilibrium and Le Chatelier’s principle, the equilibrium constant Kc, and Kp for homogeneous gaseous systems (A-level only).

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3.1.7 · Paper 1

Oxidation, Reduction and Redox Equations

Oxidation states, electron-transfer definitions, and constructing half-equations and overall redox equations.

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3.1.8 · Paper 1 A2

Thermodynamics

Born–Haber cycles, enthalpies of solution, entropy and Gibbs free-energy change ΔG = ΔH − TΔS.

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3.1.9 · Paper 2 A2

Rate Equations

Rate equations and orders of reaction, determining the rate constant, the Arrhenius equation and the rate-determining step.

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3.1.11 · Paper 1 A2

Electrode Potentials and Electrochemical Cells

Standard electrode potentials, the electrochemical series, cell EMF, and commercial cells including fuel cells.

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3.1.12 · Paper 1 A2

Acids and Bases

Brønsted–Lowry theory, pH, Ka and Kw calculations, titration curves, indicators and buffer action.

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Inorganic chemistry

Sections 3.2.1–3.2.6, all examined on Paper 1.

Organic chemistry

Sections 3.3.1–3.3.16, all examined on Paper 2.

3.3.1 · Paper 2

Introduction to Organic Chemistry

Formulae and IUPAC naming, structural and E–Z isomerism, functional groups and homologous series, and curly-arrow mechanisms.

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3.3.2 · Paper 2

Alkanes

Fractional distillation and cracking of crude oil, complete and incomplete combustion and its pollutants, and free-radical substitution.

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3.3.3 · Paper 2

Halogenoalkanes

Nucleophilic substitution with OH, CN and NH3, the C–X bond-enthalpy rate trend, elimination vs substitution, and ozone depletion by CFCs.

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3.3.4 · Paper 2

Alkenes

The C=C double bond, electrophilic addition with HBr, H2SO4 and Br2, carbocation stability and major products, and addition polymers.

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3.3.5 · Paper 2

Alcohols

Oxidation to aldehydes, ketones and carboxylic acids, elimination to alkenes, and ethanol production and biofuels.

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3.3.6 · Paper 2

Organic Analysis

Test-tube identification of functional groups, and structure determination by mass spectrometry and infrared spectroscopy.

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3.3.7 · Paper 2 A2

Optical Isomerism

Chirality, enantiomers and racemic mixtures, and why optical isomers rotate plane-polarised light.

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3.3.8 · Paper 2 A2

Aldehydes and Ketones

Oxidation and reduction of carbonyls, nucleophilic addition mechanisms, and hydroxynitrile formation.

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3.3.9 · Paper 2 A2

Carboxylic Acids and Derivatives

Weak acids, esters and hydrolysis, fats, soap and biodiesel, and the addition–elimination chemistry of acyl chlorides and anhydrides.

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3.3.10 · Paper 2 A2

Aromatic Chemistry

The bonding and stability of benzene, and electrophilic substitution: nitration and Friedel–Crafts acylation.

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3.3.11 · Paper 2 A2

Amines

Preparation of amines, base strength and nucleophilicity, and the reactions of primary aliphatic and aromatic amines.

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3.3.12 · Paper 2 A2

Polymers

Condensation polymers — polyesters and polyamides — their hydrolysis, biodegradability and comparison with addition polymers.

3.3.13 · Paper 2 A2

Amino Acids, Proteins and DNA

Zwitterions and the ions amino acids form at any pH, the peptide link and protein structure, TLC, enzymes and stereospecific active sites, DNA base pairing and cisplatin.

3.3.14 · Paper 2 A2

Organic Synthesis

Multi-step synthesis routes connecting every functional group on the course — the synoptic heart of Paper 2.

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3.3.15 · Paper 2 A2

NMR Spectroscopy

¹H and ¹³C NMR interpretation — chemical shifts, integration, splitting patterns, TMS and deuterated solvents.

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3.3.16 · Paper 2 A2

Chromatography

The balance between the moving and stationary phases, TLC and Rf values with Required Practical 12, column chromatography, and gas chromatography with GC–MS.

Required practicals

All 12 required practical activities — RP1–6 (AS & A-Level) and RP7–12 (A-level only) — collated on a single page. Paper 3 includes 40 marks on practical techniques and data analysis.

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